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1,3-Bis(diphenylphosphino)propane, 97%

Codice prodotto. 11439763
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Codice prodotto. 11439763 Fornitore Thermo Scientific Alfa Aesar N. del fornitore A12931.22
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Spedizione stimata: 24-11-2026
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CAS: 6737-42-4 | C27H26P2 | 412.45 g/mol

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

Solubility
Insoluble in water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 6737-42-4
Formula molecolare C27H26P2
Molecular Weight (g/mol) 412.45
Numero MDL MFCD00003050
InChI Key LVEYOSJUKRVCCF-UHFFFAOYSA-N
Sinonimo 1,3-bis diphenylphosphino propane, dppp, trimethylenebis diphenylphosphine, phosphine, 1,3-propanediylbis diphenyl, 3-diphenylphosphanyl propyl diphenylphosphane, 3-diphenylphosphanylpropyl diphenyl phosphane, 1,3-bis diphenyphosphino propane, 1,3-bis diphenylphosphino propane dppp, bis 1,3-diphenylphosphino propane, 1,3-bis-diphenylphosphino propane
PubChem CID 81219
IUPAC Name 3-diphenylphosphanylpropyl(diphenyl)phosphane
SMILES C(CP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1

Specifica

Materiale o nome chimico 1,3-Bis(diphenylphosphino)propane
Punto di fusione 58°C to 63°C
Formula lineare (C6H5)2P(CH2)3P(C6H5)2
Quantità 100 g
Beilstein 2821785
Sensibilità Air Sensitive
Informazioni di solubilità Insoluble in water.
Peso formulazione 412.46
Percent Purity 97%

RUO – Research Use Only

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