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  8. [Bis(trifluoroacetoxy)iodo]benzene, 97%

[Bis(trifluoroacetoxy)iodo]benzene, 97%

Codice prodotto. 11368166
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Codice prodotto. Quantità Dimensione della confezione
11368166 5 g 5g
11378166 25 g 25g
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Codice prodotto. 11368166 Fornitore Thermo Scientific Alfa Aesar N. del fornitore L15141.06
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Descrizione

CAS: 2712-78-9 | C10H5F6IO4 | 430.041 g/mol

[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

Solubility
Insoluble in water.

Notes
Light and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 2712-78-9
Formula molecolare C10H5F6IO4
Molecular Weight (g/mol) 430.041
Numero MDL MFCD00009672
InChI Key PEZNEXFPRSOYPL-UHFFFAOYSA-N
Sinonimo bis trifluoroacetoxy iodo benzene, pifa, unii-659sfv27xs, bis-trifluoroacetoxyiodobenzene, phenylbis trifluoroacetato-o iodine, bis i,i-trifluoroacetoxy iodobenzene, iodine, phenylbis trifluoroacetato-o, bis trifluoracetoxy-iodobenzene, bis trifluoroacetoxy phenyl iodane
PubChem CID 102317
IUPAC Name [phenyl-(2,2,2-trifluoroacetyl)oxy-$l^{3}-iodanyl] 2,2,2-trifluoroacetate
SMILES C1=CC=C(C=C1)I(OC(=O)C(F)(F)F)OC(=O)C(F)(F)F

Specifica

Materiale o nome chimico [Bis(trifluoroacetoxy)iodo]benzene
Punto di fusione 122°C to 125°C
Quantità 5 g
Beilstein 764767
Sensibilità Light and moisture sensitive
Informazioni di solubilità Insoluble in water.
Peso formulazione 430.04
Percent Purity 97%

RUO – Research Use Only

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