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Chloromethyl methyl sulfide, 94%

Codice prodotto. 11393036
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Quantità:
10 g
50 g
Dimensione della confezione:
10g
50g
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Codice prodotto. 11393036

Marca: Thermo Scientific Alfa Aesar L10858.18

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CAS: 2373-51-5 | C2H5ClS | 96.57 g/mol

Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.

Solubility
Soluble in acetonitrile, ether and dichloromethane. Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8°C. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 2373-51-5
Formula molecolare C2H5ClS
Molecular Weight (g/mol) 96.57
Numero MDL MFCD00000923
InChI Key JWMLCCRPDOIBAV-UHFFFAOYSA-N
Sinonimo chloromethyl methyl sulfide, chlorodimethyl sulfide, methylthiomethyl chloride, chloro methylthio methane, methane, chloro methylthio, chlorodimethyl thioether, chloromethyl methyl thioether, monochlorodimethyl sulfide, chloro methylsulfanyl methane, clorodimetilsolfuro
PubChem CID 16916
IUPAC Name chloro(methylsulfanyl)methane
SMILES CSCCl

Specifica

Materiale o nome chimico Chloromethyl methyl sulfide
Densità 1.16
Punti di ebollizione 104°C to 105°C
Punto d'infiammabilità 17°C (62°F)
Odore Stench
Indice di rifrazione 1.498
Quantità 50 g
Numero UN UN1993
Beilstein 1730851
Sensibilità Moisture sensitive
Informazioni di solubilità Soluble in acetonitrile,ether and dichloromethane. Insoluble in water.
Peso formulazione 96.58
Percent Purity 95%
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RUO – Research Use Only

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