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Di-tert-butylchlorophosphine, 96%

Codice prodotto. 11335349
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Codice prodotto. 11335349 Fornitore Thermo Scientific Alfa Aesar N. del fornitore B20998.14
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Descrizione

CAS: 13716-10-4 | C8H18ClP | 180.656 g/mol

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Miscible with terahydrofuran.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.
TRUSTED_SUSTAINABILITY

Kemiska identifierare

CAS 13716-10-4
Formula molecolare C8H18ClP
Molecular Weight (g/mol) 180.656
Numero MDL MFCD00008815
InChI Key MCRSZLVSRGTMIH-UHFFFAOYSA-N
Sinonimo di-tert-butylchlorophosphine, di-tert-butylchlorophosphane, di-t-butylchlorophosphine, phosphinous chloride, bis 1,1-dimethylethyl, chlorodi-tert-butylphosphine, phosphinous chloride, di-tert-butyl, di-tert-butyl chloro phosphane, di-tert-butylphosphinous chloride, clptbu2, pubchem6477
PubChem CID 139566
IUPAC Name ditert-butyl(chloro)phosphane
SMILES CC(C)(C)P(C(C)(C)C)Cl

Specifikationer

Materiale o nome chimico Di-tert-butylchlorophosphine
Densità 0.951
Punti di ebollizione 47°C to 49°C (3 mmHg)
Punto d'infiammabilità 62°C (144°F)
Odore Acrid
Formula lineare [(CH3)3C]2PCl
Indice di rifrazione 1.484
Quantità 25 g
Numero UN UN3265
Sensibilità Air and moisture sensitive
Informazioni di solubilità Miscible with terahydrofuran.
Peso formulazione 180.66
Percent Purity 96%
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RUO – Research Use Only

Produkttitel
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