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  7. (+)-Diethyl L-tartrate, 98%

(+)-Diethyl L-tartrate, 98%

Codice prodotto. 11433374
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Codice prodotto. 11433374 Fornitore Thermo Scientific Alfa Aesar N. del fornitore A10641.30
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Descrizione

CAS: 87-91-2 | C8H14O6 | 206.19 g/mol

(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

Solubility
Fully miscible in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 87-91-2
Formula molecolare C8H14O6
Molecular Weight (g/mol) 206.19
Numero MDL MFCD00009143
InChI Key YSAVZVORKRDODB-UHFFFAOYNA-N
Sinonimo diethyl l-+-tartrate, 2r,3r-diethyl 2,3-dihydroxysuccinate, l +-diethyl l-tartrate, +-diethyl l-tartrate, diethyl l-tartrate, diethyl-l-tartrate, unii-oq72cpy58z, l-+-tartaric acid diethyl ester, diethyl l-tartarate, tartaric acid, diethyl ester, r,r
PubChem CID 6993580
SMILES CCOC(=O)C(O)C(O)C(=O)OCC

Specifica

Materiale o nome chimico (+)-Diethyl L-tartrate
Punto di fusione 17°C
Densità 1.205
Punti di ebollizione 280°C
Punto d'infiammabilità 93°C (199°F)
Indice di rifrazione 1.446
Quantità 250 g
Beilstein 1727145
Indice di Merck 14,3855
Informazioni di solubilità Fully miscible in water.
Optical Rotation +27° (c=1 in water)
IUPAC Name diethyl (2R,3R)-2,3-dihydroxybutanedioate
Peso formulazione 206.19
Percent Purity 98%
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RUO – Research Use Only

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