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Hexaethyl phosphorous triamide, 97%, Thermo Scientific Chemicals

Catalog Number 11404124
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Quantità:
5 g
25 g
100 g
Les retours ne sont pas autorisés pour ce produit. Consulta la politica di reso
2283-11-6
MFCD00009041
Les retours ne sont pas autorisés pour ce produit. Consulta la politica di reso
2283-11-6
MFCD00009041

Hexaethyl phosphorous triamide is used in the Barton syntheses of hindered alkenes, involving desulfurization of small-ring heterocycles with elimination of nitrogen or carbon dioxide. It is also used as a reagent for selective vicinal dehalogenation of halogenated alkanes to give perhalogenated alkenes. The method has potential for the synthesis of highly fluorinated and mixed fluoro-halo alkenes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Hexaethyl phosphorous triamide is used in the Barton syntheses of hindered alkenes, involving desulfurization of small-ring heterocycles with elimination of nitrogen or carbon dioxide. It is also used as a reagent for selective vicinal dehalogenation of halogenated alkanes to give perhalogenated alkenes. The method has potential for the synthesis of highly fluorinated and mixed fluoro-halo alkenes.

Solubility
Insoluble in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents. It is sensitive to air. Store under dry inert gas.
TRUSTED_SUSTAINABILITY
Materiale o nome chimico Hexaethyl phosphorous triamide
Densità 0.903
Punti di ebollizione 245°C to 246°C
Punto d'infiammabilità 58°C (136°F)
Formula molecolare C12H30N3P
Indice di rifrazione 1.4737
Quantità 25 g
Numero UN UN1993
Beilstein 636187
Sensibilità Air Sensitive
Sinonimo tris diethylamino phosphine, hexaethylphosphorous triamide, hexaethyl phosphorous triamide, phosphorous triamide, hexaethyl, hexaethyltriaminophosphine, n,n,n',n',n,n-hexaethylphosphinetriamine, tris n,n-diethylamino phosphine, hexaethylphosphoruo triamide, hexaethylphosphorus triamide, phosphorous triamide, n,n,n',n',n,n-hexaethyl
Informazioni di solubilità Insoluble in water.
InChI Key FDIOSTIIZGWENY-UHFFFAOYSA-N
SMILES CCN(CC)P(N(CC)CC)N(CC)CC
IUPAC Name N-[bis(diethylamino)phosphanyl]-N-ethylethanamine
Molecular Weight (g/mol) 247.37
PubChem CID 75292
Peso formulazione 247.37
Percent Purity 97%
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RUO – Research Use Only

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