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m-Anisidine, 98%
Descrizione
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.
Solubility
Soluble in water(18g/L).
Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Specifica
Specifica
| Materiale o nome chimico | m-Anisidine |
| Punto di fusione | -1°C |
| Densità | 1.101 |
| Punti di ebollizione | 250°C to 251°C |
| Punto d'infiammabilità | 126°C (258°F) |
| Odore | Characteristic |
| Indice di rifrazione | 1.581 |
| Quantità | 50 g |
| Numero UN | UN2431 |
| Beilstein | 386119 |
| Vedi altri risultati |
Safety and Handling
- m-Anisidine
- Pericolo
- Tossicità acuta Categoria 3
- Tossicità acuta Categoria 4
- PERICOLO A LUNGO TERMINE PER L'AMBIENTE ACQUATICO Cronico 1
- PERICOLO ACUTO PER L'AMBIENTE ACQUATICO Acuto 1
- Tossicità specifica per organi bersaglio (esposizione ripetuta) Categoria 2
- H302-Nocivo se ingerito.
- H311-Tossico per contatto con la pelle.
- H332-Nocivo se inalato.
- H373-Può provocare danni agli organi.
- H400-Molto tossico per gli organismi acquatici.
- H410-Molto tossico per gli organismi acquatici con effetti di lunga durata.
- P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
- P301+P330+P331-IN CASO DI INGESTIONE: sciacquare la bocca. NON provocare il vomito.
- P302+P352-IN CASO DI CONTATTO CON LA PELLE: lavare abbondantemente con acqua/.
- P304+P340-IN CASO DI INALAZIONE: trasportare l'infortunato all'aria aperta e mantenerlo a riposo in posizione che favorisca la respirazione.
- P312-Contattare un CENTRO ANTIVELENI/un medico/in caso di malessere.
- MIXTURE LIST-Contiene: m-Anisidine
RUO – Research Use Only
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