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m-Anisidine, 98%

Codice prodotto. 11459752
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50 g
250 g
1000 g
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1000g
250g
50g
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Codice prodotto. 11459752

Marca: Thermo Scientific Alfa Aesar A10815.18

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CAS: 536-90-3 | C7H9NO | 123.155 g/mol

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Solubility
Soluble in water(18g/L).

Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 536-90-3
Formula molecolare C7H9NO
Molecular Weight (g/mol) 123.155
Numero MDL MFCD00007783
InChI Key NCBZRJODKRCREW-UHFFFAOYSA-N
Sinonimo m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i
PubChem CID 10824
IUPAC Name 3-methoxyaniline
SMILES COC1=CC=CC(=C1)N

Specifica

Materiale o nome chimico m-Anisidine
Punto di fusione -1°C
Densità 1.101
Punti di ebollizione 250°C to 251°C
Punto d'infiammabilità 126°C (258°F)
Odore Characteristic
Indice di rifrazione 1.581
Quantità 50 g
Numero UN UN2431
Beilstein 386119
Sensibilità Light sensitive
Indice di Merck 14,667
Informazioni di solubilità Soluble in water(18g/L).
Peso formulazione 123.16
Percent Purity 98%
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Product Identifier
  • m-Anisidine
Signal Word
  • Pericolo
Hazard Category
  • Tossicità acuta Categoria 3
  • Tossicità acuta Categoria 4
  • PERICOLO A LUNGO TERMINE PER L'AMBIENTE ACQUATICO Cronico 1
  • PERICOLO ACUTO PER L'AMBIENTE ACQUATICO Acuto 1
  • Tossicità specifica per organi bersaglio (esposizione ripetuta) Categoria 2
Hazard Statement
  • H302-Nocivo se ingerito.
  • H311-Tossico per contatto con la pelle.
  • H332-Nocivo se inalato.
  • H373-Può provocare danni agli organi.
  • H400-Molto tossico per gli organismi acquatici.
  • H410-Molto tossico per gli organismi acquatici con effetti di lunga durata.
Precautionary Statement
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P301+P330+P331-IN CASO DI INGESTIONE: sciacquare la bocca. NON provocare il vomito.
  • P302+P352-IN CASO DI CONTATTO CON LA PELLE: lavare abbondantemente con acqua/.
  • P304+P340-IN CASO DI INALAZIONE: trasportare l'infortunato all'aria aperta e mantenerlo a riposo in posizione che favorisca la respirazione.
  • P312-Contattare un CENTRO ANTIVELENI/un medico/in caso di malessere.
Supplemental information
  • MIXTURE LIST-Contiene: m-Anisidine

RUO – Research Use Only

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