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  8. N-Fluorobenzenesulfonimide, 97%

N-Fluorobenzenesulfonimide, 97%

Codice prodotto. 11328855
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25 g
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Codice prodotto. 11328855 Fornitore Thermo Scientific Alfa Aesar N. del fornitore L13955.14
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Descrizione

CAS: 133745-75-2 | C12H10FNO4S2 | 315.333 g/mol

N-Fluorobenzenesulfonimide fluorinates aromatics, enolates, azaenolates and carbanions in high yield. It is used for diastereoselective fluorination of Li enolates of chiral carboximides, for directed fluorination of ortho-lithiated aromatics and for a review of electrophilic N-F fluorinating agents. Asymmteric fluorinations is effected in the presence of a Pd-BINAP catalyst system at room temperature in an ionic liquid. It is a reagent employed in a palladium-catalyzed enantioselective fluorination of t-butoxycarbonyl lactones and lactams. It is also used in the electrophilic difluorination of dihalopyridines with butyl lithium and in the direct conversion of alcohols to dibenzenesulfonamides with triphenylphosphine.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
N-Fluorobenzenesulfonimide fluorinates aromatics, enolates, azaenolates and carbanions in high yield. It is used for diastereoselective fluorination of Li enolates of chiral carboximides, for directed fluorination of ortho-lithiated aromatics and for a review of electrophilic N-F fluorinating agents. Asymmteric fluorinations is effected in the presence of a Pd-BINAP catalyst system at room temperature in an ionic liquid. It is a reagent employed in a palladium-catalyzed enantioselective fluorination of t-butoxycarbonyl lactones and lactams. It is also used in the electrophilic difluorination of dihalopyridines with butyl lithium and in the direct conversion of alcohols to dibenzenesulfonamides with triphenylphosphine.

Solubility
Very soluble in acetonitrile, dichloromethane or THF and less soluble in toluene.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 133745-75-2
Formula molecolare C12H10FNO4S2
Molecular Weight (g/mol) 315.333
Numero MDL MFCD00144885
InChI Key RLKHFSNWQCZBDC-UHFFFAOYSA-N
Sinonimo n-fluorobenzenesulfonimide, nfsi, n-fluoro-n-phenylsulfonyl benzenesulfonamide, n-fluorodibenzenesulfonimide, n-fluorobenzensulfonimide, n-fluorobenzenesulphonimide, accufluor nfsi, n-fluorodi benzenesulfonyl amine, bis phenylsulfonyl fluoroamine, n-fluorobis phenylsulfonyl amine
PubChem CID 588007
IUPAC Name N-(benzenesulfonyl)-N-fluorobenzenesulfonamide
SMILES C1=CC=C(C=C1)S(=O)(=O)N(F)S(=O)(=O)C2=CC=CC=C2

Specifica

Materiale o nome chimico N-Fluorobenzenesulfonimide
Punto di fusione 114°C to 118°C
Quantità 25 g
Beilstein 5348902
Informazioni di solubilità Very soluble in acetonitrile,dichloromethane or THF and less soluble in toluene.
Peso formulazione 315.34
Percent Purity 97%

RUO – Research Use Only

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