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  7. N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine, 94%

N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine, 94%

Codice prodotto. 11328716
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Quantità:
1 g
5 g
Dimensione della confezione:
1g
5g
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Codice prodotto. 11328716

Marca: Thermo Scientific Alfa Aesar L19412.06

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Descrizione

CAS: 93102-05-7 | C13H23NOSi | 237.418 g/mol

N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine forms azomethine ylides which readily undergo [3+2] cycloaddition to α,β-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields. It reacts with asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines. It is used in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine forms azomethine ylides which readily undergo [3+2] cycloaddition to α,ß-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields. It reacts with asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines. It is used in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds.

Solubility
Soluble in chloroform, ethyl acetate.

Notes
Moisture & Light Sensitive. Store away from oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 93102-05-7
Formula molecolare C13H23NOSi
Molecular Weight (g/mol) 237.418
Numero MDL MFCD00674005
InChI Key RPZAAFUKDPKTKP-UHFFFAOYSA-N
Sinonimo n-methoxymethyl-n-trimethylsilylmethyl benzylamine, n-benzyl-1-methoxy-n-trimethylsilyl methyl methanamine, benzyl methoxymethyl trimethylsilyl methyl amine, benzyl-methoxymethyl-trimethylsilanylmethyl-amine, n-benzyl-n-methoxymethyl-n-trimethylsilylmethylamine, n-benzyl-n-methoxymethyl trimethylsilylmethylamine, n-methoxymethyl phenyl-n-trimethylsilyl methyl methanamine, n-methoxymethyl-n-trimethylsilyl methyl phenyl, n-methoxymethyl-n-trimethylsilylmethyl-benzylamine
PubChem CID 353442
IUPAC Name N-(methoxymethyl)-1-phenyl-N-(trimethylsilylmethyl)methanamine
SMILES COCN(CC1=CC=CC=C1)C[Si](C)(C)C

Specifica

Materiale o nome chimico N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine
Densità 0.928
Punti di ebollizione 76°C (0.3 mmHg)
Punto d'infiammabilità 66°C (150°F)
Indice di rifrazione 1.492
Quantità 5 g
Beilstein 4311216
Sensibilità Light and moisture sensitive
Informazioni di solubilità Soluble in chloroform,ethyl acetate.
Peso formulazione 237.42
Percent Purity 94%
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RUO – Research Use Only

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