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tert-Butyl hydroperoxide, 70% aq. soln.

Codice prodotto. 11471648
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Product Code. 11471648 Supplier Thermo Scientific Alfa Aesar Supplier No. A13926.0F
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Description

CAS: 75-91-2 | C4H10O2 | 90.122 g/mol

tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

Solubility
Miscible with water and diethyl ether.

Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 75-91-2
Formula molecolare C4H10O2
Molecular Weight (g/mol) 90.122
Numero MDL MFCD00002130
InChI Key CIHOLLKRGTVIJN-UHFFFAOYSA-N
Sinonimo tert-butyl hydroperoxide, tbhp, t-butyl hydroperoxide, tert-butylhydroperoxide, perbutyl h, t-butylhydroperoxide, cadox tbh, hydroperoxide, 1,1-dimethylethyl, 1,1-dimethylethyl hydroperoxide, terc. butylhydroperoxid
PubChem CID 6410
ChEBI CHEBI:64090
IUPAC Name 2-hydroperoxy-2-methylpropane
SMILES CC(C)(C)OO

Specifications

Materiale o nome chimico tert-Butyl hydroperoxide
Punto di fusione -3°C
Densità 0.937
Punti di ebollizione 96°C (decomposition)
Punto d'infiammabilità 43°C (109°F)
Intervallo percentuale saggio 70% Aqueous Solution
Formula lineare (CH3)3COOH
Indice di rifrazione 1.387
Quantità 2500 mL
Numero UN UN3109
Beilstein 1098280
Indice di Merck 14,1570
Informazioni di solubilità Miscible with water and diethyl ether.
Peso formulazione 90.12
Concentration or Composition (by Analyte or Components) 70% aq. soln.
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