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  7. tert-Butyl nitrite, tech. 90%

tert-Butyl nitrite, tech. 90%

Codice prodotto. 11392897
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Codice prodotto. 11392897 Fornitore Thermo Scientific Alfa Aesar N. del fornitore L16135.22
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Beschreibung

CAS: 540-80-7 | C4H9NO2 | 103.121 g/mol

tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Solubility
Miscible with diethyl ether, chloroform, alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.

Notes
Light sensitive. Store in cool place. Incompatible with strong reducing agents, powdered metals and strong acids.
TRUSTED_SUSTAINABILITY

Chemische Identifikatoren

CAS 540-80-7
Formula molecolare C4H9NO2
Molecular Weight (g/mol) 103.121
Numero MDL MFCD00002055
InChI Key IOGXOCVLYRDXLW-UHFFFAOYSA-N
Sinonimo t-butyl nitrite, 1,1-dimethylethyl nitrite, tert-butylnitrite, nitrous acid, 1,1-dimethylethyl ester, unii-4780h7u8lu, ccris 2098, alpha,alpha-dimethylethyl nitrite, nitrous acid, t-butyl ester, 2-methyl-2-propylnitrit, ch3 3cono
PubChem CID 10906
IUPAC Name tert-butyl nitrite
SMILES CC(C)(C)ON=O

Spezifikation

Materiale o nome chimico tert-Butyl nitrite
Densità 0.867
Punti di ebollizione 61°C to 63°C
Punto d'infiammabilità −23°C (−9°F)
Odore Sweet
Indice di rifrazione 1.369
Quantità 100 g
Numero UN UN2351
Beilstein 1209339
Indice di Merck 14,1583
Informazioni di solubilità Miscible with diethyl ether,chloroform,alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.
Peso formulazione 103.12
Percent Purity 90%
Grado Caratteristiche
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Sicherheit und Handhabung

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Produktidentifikator
  • tert-Butyl nitrite
 Signalwort
  • Pericolo
 Gefahrenkategorie
  • Tossicità acuta Categoria 4
  • Liquido infiammabile Categoria 2
 Gefahrenhinweis
  • H225-Liquido e vapori facilmente infiammabili.
  • H302-Nocivo se ingerito.
  • H332-Nocivo se inalato.
 Sicherheitshinweis
  • P210-Tenere lontano da fonti di calore, superfici riscaldate, scintille, fiamme e altre fonti di innesco. Vietato fumare.
  • P261-Evitare di respirare la polvere/i fumi/i gas/la nebbia/i vapori/gli aerosol.
  • P301+P330+P331-IN CASO DI INGESTIONE: sciacquare la bocca. NON provocare il vomito.
  • P303+P361+P353-IN CASO DI CONTATTO CON LA PELLE (o con i capelli): togliere immediatamente tutti gli indumenti contaminati. Sciacquare la pelle/fare una doccia.
  • P304+P340-IN CASO DI INALAZIONE: trasportare l'infortunato all'aria aperta e mantenerlo a riposo in posizione che favorisca la respirazione.
  • P312-Contattare un CENTRO ANTIVELENI/un medico/in caso di malessere.
 Ergänzende Informationen
  • MIXTURE LIST-Contain: tert-Butyl nitrite
Sicherheitsdatenblatt (SDS)

RUO – Research Use Only

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