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Tetrachlorophthalic anhydride, 98%

Codice prodotto. 11477997
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Codice prodotto. 11477997 Fornitore Thermo Scientific Alfa Aesar N. del fornitore A17404.36
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CAS: 117-08-8 | C8Cl4O3 | 285.885 g/mol

Protection of amines as their tetrachlorophthalimide derivatives, by reaction with the anhydride in the presence of triethylamine, has been found to be useful in oligosaccharide chemistry. The group is stable to a wide range of reagents but can be selectively cleaved with ethylenediamine at lower temperatures than for the parent phthalimide derivatives; in particular, carboxylic esters are not cleaved under these conditions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Protection of amines as their tetrachlorophthalimide derivatives, by reaction with the anhydride in the presence of triethylamine, has been found to be useful in oligosaccharide chemistry. The group is stable to a wide range of reagents but can be selectively cleaved with ethylenediamine at lower temperatures than for the parent phthalimide derivatives; in particular, carboxylic esters are not cleaved under these conditions.

Solubility
Hydrolyzes slowly in water.

Notes
Hygroscopic. Store away from oxidizing agents, acids.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 117-08-8
Formula molecolare C8Cl4O3
Molecular Weight (g/mol) 285.885
Numero MDL MFCD00005920
InChI Key AUHHYELHRWCWEZ-UHFFFAOYSA-N
Sinonimo tetrachlorophthalic anhydride, tetrathal, 4,5,6,7-tetrachloro-1,3-isobenzofurandione, niagathal, 1,3-isobenzofurandione, 4,5,6,7-tetrachloro, phthalic anhydride, tetrachloro, 4,5,6,7-tetrachloroisobenzofuran-1,3-dione, 1,3-dioxy-4,5,6,7-tetrachloroisobenzofuran, unii-76glw0lbek, ccris 6202
PubChem CID 8326
ChEBI CHEBI:59097
IUPAC Name 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione
SMILES C12=C(C(=C(C(=C1Cl)Cl)Cl)Cl)C(=O)OC2=O

Specifica

Materiale o nome chimico Tetrachlorophthalic anhydride
Punto di fusione 254°C to 258°C
Punti di ebollizione 349°C to 354°C
Punto d'infiammabilità 362°C (683°F)
Odore Weak
Quantità 500 g
Numero UN UN3077
Beilstein 211560
Sensibilità Moisture sensitive
Informazioni di solubilità Hydrolyzes slowly in water.
Peso formulazione 285.9
Percent Purity 98%
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