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  7. Triethyl phosphonoacetate, 98+%

Triethyl phosphonoacetate, 98+%

Codice prodotto. 11438086
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Codice prodotto. 11438086 Fornitore Thermo Scientific Alfa Aesar N. del fornitore A14120.22
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Descrizione

CAS: 867-13-0 | C8H17O5P | 224.193 g/mol

Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.

Solubility
Slightly miscible with water.

Notes
Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 867-13-0
Formula molecolare C8H17O5P
Molecular Weight (g/mol) 224.193
Numero MDL MFCD00009177
InChI Key GGUBFICZYGKNTD-UHFFFAOYSA-N
Sinonimo triethyl phosphonoacetate, ethyl 2-diethoxyphosphoryl acetate, ethyl diethoxyphosphoryl acetate, ethyl diethylphosphono acetate, triethyl phosphonoethanoate, diethyl carboethoxymethylphosphonate, diethyl ethoxycarbonylmethanephosphonate, diethylphosphonoacetic acid ethyl ester, diethyl carbethoxymethylphosphonate
PubChem CID 13345
IUPAC Name ethyl 2-diethoxyphosphorylacetate
SMILES CCOC(=O)CP(=O)(OCC)OCC

Specifica

Materiale o nome chimico Triethyl phosphonoacetate
Punto di fusione -24°C
Densità 1.125
Punti di ebollizione 260°C to 262°C
Punto d'infiammabilità 165°C (329°F)
Indice di rifrazione 1.431
Quantità 100 g
Beilstein 1343714
Informazioni di solubilità Slightly miscible with water.
Peso formulazione 224.19
Percent Purity ≥98%
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Safety and Handling

compliance-icons
Product Identifier
  • Triethyl phosphonoacetate
 Signal Word
  • Pericolo
 Hazard Category
  • Lesione oculare grave/irritazione oculare Categoria 1
  • Corrosione/irritazione della pelle Categoria 2
  • Tossicità specifica per organi bersaglio (esposizione singola) Categoria 3
 Hazard Statement
  • H315-Provoca irritazione cutanea.
  • H318-Provoca gravi lesioni oculari.
  • H335-Può irritare le vie respiratorie.
 Precautionary Statement
  • P261-Evitare di respirare la polvere/i fumi/i gas/la nebbia/i vapori/gli aerosol.
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P302+P352-IN CASO DI CONTATTO CON LA PELLE: lavare abbondantemente con acqua/.
  • P305+P351+P338-IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti. Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
  • P310-Contattare immediatamente un CENTRO ANTIVELENI/un medico .
 Supplemental information
  • MIXTURE LIST-Contain: Triethyl phosphonoacetate

RUO – Research Use Only

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