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  7. Triisopropylsilane, 98%

Triisopropylsilane, 98%

Codice prodotto. 11322157
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Codice prodotto. 11322157 Fornitore Thermo Scientific Alfa Aesar N. del fornitore L09585.22
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Description

CAS: 6485-79-6 | C9H22Si | 158.36 g/mol

Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.

Solubility
Immiscible with water.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong acids and strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Identifiants chimiques

CAS 6485-79-6
Formula molecolare C9H22Si
Molecular Weight (g/mol) 158.36
Numero MDL MFCD00009657
InChI Key YDJXDYKQMRNUSA-UHFFFAOYSA-N
Sinonimo triisopropylsilane, tris propan-2-yl silane, triisopropyl silane, tri propan-2-yl silicon, tri-isopropylsilyl radical, triisopropylsilyl, tri-iso-propylsilane, ambotzrl-1102, pubchem12855
PubChem CID 6327611
SMILES CC(C)[SiH](C(C)C)C(C)C

Spécification

Punti di ebollizione 166°C
Materiale o nome chimico Triisopropylsilane
Quantità 100 g
Formula lineare [(CH3)2CH]3SiH
Numero UN UN1993
Beilstein 1733718
Punto d'infiammabilità 35°C (95°F)
Informazioni di solubilità Immiscible with water.
IUPAC Name tri(propan-2-yl)silicon
Peso formulazione 158.36
Percent Purity 98%
Odore Mild
Indice di rifrazione 1.434
Densità 0.773
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Sécurité et traitement

compliance-icons compliance-icons
Identifiant produit
  • Triisopropylsilane
 Mention d'avertissement
  • Attenzione
 Catégorie de danger
  • Lesione oculare grave/irritazione oculare Categoria 2
  • Liquido infiammabile Categoria 3
  • Corrosione/irritazione della pelle Categoria 2
  • Tossicità specifica per organi bersaglio (esposizione singola) Categoria 3
 Mention de danger
  • H226-Liquido e vapori infiammabili.
  • H315-Provoca irritazione cutanea.
  • H319-Provoca grave irritazione oculare.
  • H335-Può irritare le vie respiratorie.
 Conseils de prudence
  • P210-Tenere lontano da fonti di calore, superfici riscaldate, scintille, fiamme e altre fonti di innesco. Vietato fumare.
  • P261-Evitare di respirare la polvere/i fumi/i gas/la nebbia/i vapori/gli aerosol.
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P302+P352-IN CASO DI CONTATTO CON LA PELLE: lavare abbondantemente con acqua/.
  • P305+P351+P338-IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti. Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
 Informations supplémentaires
  • MIXTURE LIST-Contain: Triisopropylsilane
FDS

RUO – Research Use Only

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