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Trimethylsulfoxonium iodide, 98+%

Codice prodotto. 11491998
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11491998 25 g 25g
11402008 100 g 100g
11412008 500 g 500g
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Codice prodotto. 11491998 Fornitore Thermo Scientific Alfa Aesar N. del fornitore A14589.14
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Descrizione

CAS: 1774-47-6 | C3H9IOS | 220.07 g/mol

Trimethylsulfoxonium iodide reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides. Further, it reacts with alfa,beta-unsaturated esters to get cyclopropyl esters.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Trimethylsulfoxonium iodide reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides. Further, it reacts with alfa,beta-unsaturated esters to get cyclopropyl esters.

Solubility
Soluble in water.

Notes
Incompatible with strong oxidizing agents and strong bases. Light sensitive.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 1774-47-6
Formula molecolare C3H9IOS
Molecular Weight (g/mol) 220.07
Numero MDL MFCD00011899
InChI Key BPLKQGGAXWRFOE-UHFFFAOYSA-M
Sinonimo trimethylsulfoxonium iodide, trimethylsulphoxonium iodide, trimethyloxosulfonium iodide, sulfoxonium, trimethyl-, iodide, trimethyloxosulphonium iodide, trimethyl sulphoxonium ioidie, s,s,s-trimethylsulfoxonium iodide, trimethylsulfoxoniumiodide, sulfonium, trimethyl-, iodide, oxide, sulfoxonium, trimethyl-, iodide 1:1
PubChem CID 74498
IUPAC Name trimethyl(oxo)-λ⁶-sulfanylium iodide
SMILES [I-].C[S+](C)(C)=O

Specifica

Materiale o nome chimico Trimethylsulfoxonium iodide
Punto di fusione ∼170°C (decomposition)
Quantità 25 g
Beilstein 3595854
Sensibilità Light sensitive
Informazioni di solubilità Soluble in water.
Peso formulazione 220.07
Percent Purity ≥98%

RUO – Research Use Only

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