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N-Hydroxyphthalimide, 98%

Codice prodotto. 11461528
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Quantità:
100 g
500 g
2500 g
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100g
2500g
500g
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Codice prodotto. 11461528

Marca: Thermo Scientific Alfa Aesar A13862.22

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CAS: 524-38-9 | C8H5NO3 | 163.13 g/mol

Aerobic oxidation of various alcohols has been accomplished by using a new catalytic system, N-hydroxyphthalimide (NHPI) combined with Co (acac). A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature using a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and Co (OAc) 2 was developed. Novel catalysis by N-hydroxyphthalimide in the oxidation of organic substrates by molecular oxygen was described. Free radical functionalization of organic compounds catalyzed by N-hydroxyphthalimide. Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions. Hydroxylation of polycyclic alkanes with molecular oxygen catalyzed by N-hydroxyphthalimide (NHPI) combined with was transition metal salts.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Aerobic oxidation of various alcohols has been accomplished by using a new catalytic system, N-hydroxyphthalimide (NHPI) combined with Co (acac). A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature using a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and Co (OAc) 2 was developed. Novel catalysis by N-hydroxyphthalimide in the oxidation of organic substrates by molecular oxygen was described. Free radical functionalization of organic compounds catalyzed by N-hydroxyphthalimide. Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions. Hydroxylation of polycyclic alkanes with molecular oxygen catalyzed by N-hydroxyphthalimide (NHPI) combined with was transition metal salts.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 524-38-9
Formula molecolare C8H5NO3
Molecular Weight (g/mol) 163.13
Numero MDL MFCD00005891
InChI Key CFMZSMGAMPBRBE-UHFFFAOYSA-N
Sinonimo n-hydroxyphthalimide, 2-hydroxyisoindoline-1,3-dione, 2-hydroxy-1h-isoindole-1,3 2h-dione, nhpi, 2-hydroxyphthalimide, 1h-isoindole-1,3 2h-dione, 2-hydroxy, phthalimide, n-hydroxy, phthaloxime, unii-bxi99m81x0, 2-hydroxyisoindolin-1,3-dione
PubChem CID 10665
IUPAC Name 2-hydroxyisoindole-1,3-dione
SMILES ON1C(=O)C2=CC=CC=C2C1=O

Specifica

Materiale o nome chimico N-Hydroxyphthalimide
Punto di fusione ∼233°C (decomposition)
Quantità 100 g
Beilstein 131208
Indice di Merck 14,4838
Informazioni di solubilità Slightly soluble in water.
Peso formulazione 163.13
Percent Purity ≥98%

RUO – Research Use Only

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