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Triphenylphosphine, flake, 99%

Codice prodotto. 11448036
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Artikelnummer. 11448036 Lieferant Thermo Scientific Alfa Aesar Lieferanten-Nr. A14089.0I
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CAS: 603-35-0 | C18H15P | 262.29 g/mol

In the synthesis of organic compounds, phosphonium salts and other phosphorus compounds, and as a polymerization initiatorTriphenylphosphine is used in the synthesis of organic compounds due to its nucleophilicity and its reducing character. It is involved in the synthesis of biaryl compounds, phosphonium salts and other phosphorus compounds. As a reducing agent, it is used to prepare aromatic amines from the corresponding aromatic N-oxides. The anionic phosphine is usually isolated as the trisodium salt, which reacts with rhodium to form a complex that finds use in industrial hydroformylation reactions. It is also used to prepare Wilkinson's catalyst, RhCl(PPh3)3 useful to catalyze the hydrogenation of alkenes and tetrakis(triphenylphosphine)palladium(0) that is widely used to catalyse C-C coupling reactions in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
In the synthesis of organic compounds, phosphonium salts and other phosphorus compounds, and as a polymerization initiatorTriphenylphosphine is used in the synthesis of organic compounds due to its nucleophilicity and its reducing character. It is involved in the synthesis of biaryl compounds, phosphonium salts and other phosphorus compounds. As a reducing agent, it is used to prepare aromatic amines from the corresponding aromatic N-oxides. The anionic phosphine is usually isolated as the trisodium salt, which reacts with rhodium to form a complex that finds use in industrial hydroformylation reactions. It is also used to prepare Wilkinson′s catalyst, RhCl(PPh3)3 useful to catalyze the hydrogenation of alkenes and tetrakis(triphenylphosphine)palladium(0) that is widely used to catalyse C-C coupling reactions in organic synthesis.

Notes
Incompatible with oxidizing agents and acids.
TRUSTED_SUSTAINABILITY

Chemische Identifikatoren

CAS 603-35-0
Formula molecolare C18H15P
Molecular Weight (g/mol) 262.29
Numero MDL MFCD00003043 MFCD20489348
InChI Key RIOQSEWOXXDEQQ-UHFFFAOYSA-N
Sinonimo triphenylphosphine, triphenyl phosphine, phosphine, triphenyl, triphenylphosphorus, triphenyl-phosphane, triphenylphosphide, phosphorustriphenyl, trifenylfosfin, trifenylfosfin czech, triphenylphosphine resin
PubChem CID 11776
IUPAC Name triphenylphosphane
SMILES C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Spezifikation

Materiale o nome chimico Triphenylphosphine
Punto di fusione 79°C to 81°C
Densità 1.2
Punti di ebollizione 360°C
Punto d'infiammabilità 181°C (358°F)
Intervallo percentuale saggio 99%
Odore Mild
Quantità 5000 g
Beilstein 610776
Indice di Merck 14,9743
Informazioni di solubilità Insoluble in water; Soluble in benzene,acetone,carbon tetrachloride,ether,and glacial acetic acidSoluble in ether,benzene,carbon tetrachloride,glacial acetic acid,acetone,chloroform and alcohol; Insoluble in water.
Peso formulazione 262.29
Percent Purity 99%
Forma fisica Flakes
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Produktidentifikator
  • Triphenylphosphine
Signalwort
  • Attenzione
Gefahrenkategorie
  • Tossicità acuta Categoria 4
  • Sensibilizzazione della pelle Categoria 1
  • Tossicità specifica per organi bersaglio (esposizione ripetuta) Categoria 2
Gefahrenhinweis
  • H302-Nocivo se ingerito.
  • H317-Può provocare una reazione allergica cutanea.
  • H373-Può provocare danni agli organi.
Sicherheitshinweis
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P301+P312-IN CASO DI INGESTIONE accompagnata da malessere: contattare un CENTRO ANTIVELENI/medico/
Ergänzende Informationen
  • MIXTURE LIST-Contain: Triphenylphosphine

RUO – Research Use Only

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