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  8. Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min

Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min

Codice prodotto. p-4408395
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Quantità:
1 g
5 g
Dimensione della confezione:
1g
5g
Codice prodotto. Quantità unitSize
11397537 1 g 1g
11307547 5 g 5g
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Codice prodotto. 11397537

Marca: Thermo Scientific Alfa Aesar 012760.03

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Descrizione

CAS: 51364-51-3 | C51H42O3Pd2 | 915.73 g/mol

Tris(dibenzylideneacetone)dipalladium(0) is the most widely used Pd0 precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. It is used as a catalyst precursor for palladium-catalyzed carbon-nitrogen bond formation, conversion of aryl chlorides, triflates and nonaflates to nitroaromatics. It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins. It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 51364-51-3
Formula molecolare C51H42O3Pd2
Molecular Weight (g/mol) 915.73
Numero MDL MFCD00013310
InChI Key CYPYTURSJDMMMP-UHFFFAOYSA-N
Sinonimo tris dibenzylideneacetone dipalladium 0, tris dibenzylideneacetone dipalladium, pd2 dba 3, tris dibezylideneacetone dipalladium, tris dibenzylideneacetone dipalladium o, tris dibenzylideneacetonyl bis-palladium, tris dba, tris 1e,4e-1,5-diphenylpenta-1,4-dien-3-one dipalladium
PubChem CID 9811564
IUPAC Name (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium
SMILES [Pd].[Pd].O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1

Specifica

Materiale o nome chimico Tris(dibenzylideneacetone)dipalladium(0)
Punto di fusione 152°C to 155°C
Quantità 1 g
Sensibilità Air and moisture sensitive
Informazioni di solubilità Soluble in chlorinated solvents,benzene and THF.
Peso formulazione 915.74
Forma fisica Powder

Safety and Handling

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Product Identifier
  • Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min
 Signal Word
  • Attenzione
 Hazard Category
  • Sensibilizzazione della pelle Categoria 1
 Hazard Statement
  • H317-Può provocare una reazione allergica cutanea.
 Precautionary Statement
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P302+P352-IN CASO DI CONTATTO CON LA PELLE: lavare abbondantemente con acqua/.
  • P333+P313-In caso di irritazione o eruzione della pelle: consultare un medico.
 Supplemental information
  • MIXTURE LIST-Contiene: Tris(dibenzylideneacetone)dipalladium(0), Pd
SDS

RUO – Research Use Only

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