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Triethyl phosphite, 98%, Thermo Scientific Chemicals
Descrizione
Triethyl phosphite is used as a ligand in organometallic chemistry and as a reagent in organic synthesis. It is used as reference to phosphoric acid standard in 31P NMR spectroscopy. It acts as a reducing agent to prepare 2-phenylindazole from o-nitrobenzylidineaniline as well as reacts with electrophiles to get phosphonates. It forms a stable complex with copper(I) iodide. It finds application in a modified Staudinger reaction for the alkyl bromide to an amine through the azide. Further, it is also used in the preparation of 3-phenyl-2-substituted indoles by reacting with beta-nitro styrenes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Triethyl phosphite is used as a ligand in organometallic chemistry and as a reagent in organic synthesis. It is used as reference to phosphoric acid standard in 31P NMR spectroscopy. It acts as a reducing agent to prepare 2-phenylindazole from o-nitrobenzylidineaniline as well as reacts with electrophiles to get phosphonates. It forms a stable complex with copper(I) iodide. It finds application in a modified Staudinger reaction for the alkyl bromide to an amine through the azide. Further, it is also used in the preparation of 3-phenyl-2-substituted indoles by reacting with beta-nitro styrenes.
Solubility
Miscible with alcohol and ether. Immiscible with water.
Notes
Air and moisture sensitive. Incompatible with strong oxidizing agents and strong bases.
Specifica
Materiale o nome chimico | Triethyl phosphite |
Punto di fusione | -112°C |
Densità | 0.958 |
Punti di ebollizione | 155°C to 157°C |
Punto d'infiammabilità | 43°C (109°F) |
Odore | Unpleasant |
Indice di rifrazione | 1.413 |
Quantità | 100 mL |
Numero UN | UN2323 |
Beilstein | 956578 |
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Sicurezza e movimentazione
- Triethyl phosphite
- Attenzione
- Liquido infiammabile Categoria 3
- H226-Liquido e vapori infiammabili.
- P210-Tenere lontano da fonti di calore, superfici riscaldate, scintille, fiamme e altre fonti di innesco. Vietato fumare.
- P303+P361+P353-IN CASO DI CONTATTO CON LA PELLE (o con i capelli): togliere immediatamente tutti gli indumenti contaminati. Sciacquare la pelle/fare una doccia.
- P403+P233-Tenere il recipiente ben chiuso e in luogo ben ventilato.
- MIXTURE LIST-Contiene: triethyl phosphite
RUO – Research Use Only